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  17日晚上,大批中国国民党党公职人员及蓝营支持者在台北地检署外集结,抗议民进党当局利用司法整肃在野力量,打压异己,引发各界关注。

  中新社上海4月18日电(记者许婧)固态锂电池为何失效?同济大学材料科学与工程学院车用新能源研究院教授罗巍与合作者首次发现了固态锂电池金属锂负极疲劳失效现象,揭示了疲劳失效新机制,并提出了抑制疲劳失效改善固态电池性能的新策略。

  相关研究成果北京时间18日凌晨2点在线发表于国际顶尖学术期刊《科学》(Science)。

  近年来,随着新能源汽车蓬勃发展,人们对动力电池的能量密度和安全性提出了更高的要求,锂电池固态化被认为是提升电池安全和能量密度的革命性解决方案,由此,固态锂电池在全球范围内引起学术界和产业界的广泛关注。然而,在固态锂电池运行过程中,因锂枝晶生长引起的电池失效和安全隐患严重阻碍了其实际应用,需要在充分掌握电池失效机制的基础上,开发提升电池性能的新技术。

  疲劳是金属材料在受到循环载荷作用时普遍面临的问题,这种载荷会在远低于极限拉伸强度的应力水平下诱发微裂纹和断裂失效。研究团队发现,金属锂负极在受到可逆剥离/镀层引起的循环机械载荷作用时发生了由疲劳造成的失效,证明了疲劳是锂金属的固有特性,其在固态锂电池中也遵循经典的疲劳定律。这一发现是对固态锂电池现有失效机制的新认知,加深了对固态锂电池失效过程的理解。

  此研究成果不仅揭示了金属锂疲劳失效是固态锂电池循环过程中性能劣变的主要原因,同时也提出了通过增加疲劳强度来改善固态锂电池循环稳定性的新策略,对实现下一代长寿命固态锂电池具有重要的指导意义。

  美国国家加速器实验室杰出科学家、斯坦福电池中心执行主任JagjitNanda教授和美国橡树岭国家实验室高级研究员SergiyKalnaus博士在同期期刊上,对这篇论文进行了专题评述,认为“这一成果提供了固态电池电化学和机械疲劳之间的重要联系”。(完)新闻结尾 冥媒正娶陆小余全文:如何在安全的环境中享受刺激,提升生活的多样性与乐趣的相关文章
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